Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines
Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N–O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5–10 minutes in good to excellent yields.
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sg-ntu-dr.10356-1012592020-03-07T12:37:11Z Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines Qi, Xinxin Dai, Lu Park, Cheol-Min School of Physical and Mathematical Sciences Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N–O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5–10 minutes in good to excellent yields. 2013-07-09T07:26:30Z 2019-12-06T20:35:46Z 2013-07-09T07:26:30Z 2019-12-06T20:35:46Z 2012 2012 Journal Article Qi, X., Dai, L., Park, C.-M. (2012). Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines. Chemical Communications, 48(91), 11244-11246. https://hdl.handle.net/10356/101259 http://hdl.handle.net/10220/11072 10.1039/c2cc36009h en Chemical communications © 2012 The Royal Society of Chemistry. |
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Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N–O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5–10 minutes in good to excellent yields. |
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School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Qi, Xinxin Dai, Lu Park, Cheol-Min |
| format |
Article |
| author |
Qi, Xinxin Dai, Lu Park, Cheol-Min |
| spellingShingle |
Qi, Xinxin Dai, Lu Park, Cheol-Min Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines |
| author_sort |
Qi, Xinxin |
| title |
Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines |
| title_short |
Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines |
| title_full |
Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines |
| title_fullStr |
Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines |
| title_full_unstemmed |
Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines |
| title_sort |
carbenoid-mediated n–o bond insertion and its application in the synthesis of pyridines |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/101259 http://hdl.handle.net/10220/11072 |
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1681048732611641344 |