The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes

The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes

The reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling ex...

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Bibliographic Details
Main Authors: Kumaran, Elumalai, Leong, Weng Kee
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:https://hdl.handle.net/10356/101380
http://hdl.handle.net/10220/18615
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Institution: Nanyang Technological University
Language: English
Description
Summary:The reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.

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