The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes

The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes

The reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling ex...

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Main Authors: Kumaran, Elumalai, Leong, Weng Kee
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:https://hdl.handle.net/10356/101380
http://hdl.handle.net/10220/18615
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1013802023-02-28T19:22:58Z The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes Kumaran, Elumalai Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies. MOE (Min. of Education, S’pore) Accepted version 2014-01-20T02:34:47Z 2019-12-06T20:37:32Z 2014-01-20T02:34:47Z 2019-12-06T20:37:32Z 2012 2012 Journal Article Kumaran, E., & Leong, W. K. (2012). The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes. Organometallics, 31(13), 4849-4853. https://hdl.handle.net/10356/101380 http://hdl.handle.net/10220/18615 10.1021/om300387q en Organometallics © 2012 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om300387q]. 5p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
spellingShingle DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Kumaran, Elumalai
Leong, Weng Kee
The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
description The reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Kumaran, Elumalai
Leong, Weng Kee
format Article
author Kumaran, Elumalai
Leong, Weng Kee
author_sort Kumaran, Elumalai
title The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
title_short The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
title_full The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
title_fullStr The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
title_full_unstemmed The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
title_sort reaction of [cp*rhcl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(iii) complexes
publishDate 2014
url https://hdl.handle.net/10356/101380
http://hdl.handle.net/10220/18615
_version_ 1759856893238444032

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