A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion

The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography.

Saved in:

Bibliographic Details
Main Authors:	Chia, Siew-Peng, Xi, Hong Wei, Li, Yongxin, Lim, Kok Hwa, So, Cheuk-Wai
Other Authors:	School of Chemical and Biomedical Engineering
Format:	Article
Language:	English
Published:	2013
Subjects:	DRNTU::Science::Biological sciences::Biochemistry DRNTU::Science::Biological sciences::Biophysics
Online Access:	https://hdl.handle.net/10356/101466 http://hdl.handle.net/10220/16493
Tags:	Add Tag No Tags, Be the first to tag this record!
Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-101466
record_format	dspace
spelling	sg-ntu-dr.10356-1014662020-03-07T12:34:50Z A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai School of Chemical and Biomedical Engineering School of Physical and Mathematical Sciences DRNTU::Science::Biological sciences::Biochemistry DRNTU::Science::Biological sciences::Biophysics The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography. 2013-10-14T08:44:26Z 2019-12-06T20:39:00Z 2013-10-14T08:44:26Z 2019-12-06T20:39:00Z 2013 2013 Journal Article Chia, S. P., Xi, H. W., Li, Y., Lim, K. H., & So, C. W. (2013). A Base-Stabilized Lead(I) Dimer and an Aromatic Plumbylidenide Anion. Angewandte Chemie International Edition, 52(24), 6298-6301. 1433-7851 https://hdl.handle.net/10356/101466 http://hdl.handle.net/10220/16493 10.1002/anie.201301954 en Angewandte chemie international edition
institution	Nanyang Technological University
building	NTU Library
country	Singapore
collection	DR-NTU
language	English
topic	DRNTU::Science::Biological sciences::Biochemistry DRNTU::Science::Biological sciences::Biophysics
spellingShingle	DRNTU::Science::Biological sciences::Biochemistry DRNTU::Science::Biological sciences::Biophysics Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
description	The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography.
author2	School of Chemical and Biomedical Engineering
author_facet	School of Chemical and Biomedical Engineering Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai
format	Article
author	Chia, Siew-Peng Xi, Hong Wei Li, Yongxin Lim, Kok Hwa So, Cheuk-Wai
author_sort	Chia, Siew-Peng
title	A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
title_short	A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
title_full	A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
title_fullStr	A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
title_full_unstemmed	A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
title_sort	base-stabilized lead(i) dimer and an aromatic plumbylidenide anion
publishDate	2013
url	https://hdl.handle.net/10356/101466 http://hdl.handle.net/10220/16493
_version_	1681044812116000768

A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion

Similar Items