A base-stabilized lead(I) dimer and an aromatic plumbylidenide anion
The aromatic low-valent lead analogue of an indenyl anion (see scheme; 1) undergoes oxidation with SnCl2 to form the base-stabilized lead(I) dimer 2. Reduction of 2 with lithium regenerates 1. These compounds were characterized by NMR spectroscopy and X-ray crystallography.
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Main Authors: | Chia, Siew-Peng, Xi, Hong Wei, Li, Yongxin, Lim, Kok Hwa, So, Cheuk-Wai |
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Other Authors: | School of Chemical and Biomedical Engineering |
Format: | Article |
Language: | English |
Published: |
2013
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/101466 http://hdl.handle.net/10220/16493 |
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Institution: | Nanyang Technological University |
Language: | English |
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