Group II metal complexes of the germylidendiide dianion radical and germylidenide anion

• المؤلفون الرئيسيون: Chia, Siew-Peng, Carter, Emma, Xi, Hong-Wei, Li, Yongxin, So, Cheuk-Wai
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/105121; http://hdl.handle.net/10220/20658; http://dx.doi.org/10.1002/anie.201404357

The two-electron reduction of a Group 14-element(I) complex [RË⋅] (E=Ge, R=supporting ligand) to form a novel low-valent dianion radical with the composition [RË:]. 2− is reported. The reaction of [LGeCl] (1, L=2,6-(CH[DOUBLE BOND]NAr)2C6H3, Ar=2,6-iPr2C6H3) with excess calcium in THF at room temper...