Group II metal complexes of the germylidendiide dianion radical and germylidenide anion
The two-electron reduction of a Group 14-element(I) complex [RË⋅] (E=Ge, R=supporting ligand) to form a novel low-valent dianion radical with the composition [RË:]. 2− is reported. The reaction of [LGeCl] (1, L=2,6-(CH[DOUBLE BOND]NAr)2C6H3, Ar=2,6-iPr2C6H3) with excess calcium in THF at room temper...
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| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/105121 http://hdl.handle.net/10220/20658 http://dx.doi.org/10.1002/anie.201404357 |
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| Institution: | Nanyang Technological University |
| Language: | English |