Synthesis of base-stabilized heavier low valent group 14 complexes

The synthesis and the structures of group 14 element(I) dimers [LEEL] [L = 2,6-(CH=NR)2C6H3, E = Ge, Sn, Pb] and their reduction to afford the respective group 14 element anions are discussed. The treatment of [LGeGeL] and [LSnSnL] with excess KC8, afforded the germylidenide anion [LGeK.TMEDA] and s...

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Bibliographic Details
Main Author: Chia, Siew Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Theses and Dissertations
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/55388
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Institution: Nanyang Technological University
Language: English