N-phosphinoamidinato silylene- and phosphine-borylborylene complexes

This work describes a straightforward method to synthesize a borylborylene without proceeding via the rearrangement of a diborene. An amidinato amidosilylene [LSiNMe2] (L = PhC(NtBu)2) and PMe3 were reacted with an N-phosphinoamidinato diborane 1 and KC8 to form a stable silylene-borylborylene 2 and...

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Bibliographic Details
Main Authors: Fan, Jun, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Article
Language:English
Published: 2023
Subjects:
Online Access:https://hdl.handle.net/10356/168936
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Institution: Nanyang Technological University
Language: English