A pyridine-stabilized N-phosphinoamidinato N-heterocyclic carbene-diboravinyl cation: boron analogue of vinyl cation

A pyridine-stabilized N-phosphinoamidinato N-heterocyclic carbene-diboravinyl cation: boron analogue of vinyl cation

A boron analogue of vinyl cation, pyridine-stabilized N-phosphinoamidinato N-heterocyclic carbene (NHC)-diboravinyl cation 2+ , was synthesized by displacement of bromide in diborene 1 with excess pyridine. Experimental and computational studies showed that the positive charge is mainly at the B-B s...

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Bibliographic Details
Main Authors: Fan, Jun, Chia, Pei-Ting, Zhang, Zheng-Feng, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Article
Language:English
Published: 2023
Subjects:
Science::Chemistry
Boron
Diborene
Online Access:https://hdl.handle.net/10356/164639
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/164639

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