Group II metal complexes of the germylidendiide dianion radical and germylidenide anion

The two-electron reduction of a Group 14-element(I) complex [RË⋅] (E=Ge, R=supporting ligand) to form a novel low-valent dianion radical with the composition [RË:]. 2− is reported. The reaction of [LGeCl] (1, L=2,6-(CH[DOUBLE BOND]NAr)2C6H3, Ar=2,6-iPr2C6H3) with excess calcium in THF at room temper...

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Bibliographic Details
Main Authors: Chia, Siew-Peng, Carter, Emma, Xi, Hong-Wei, Li, Yongxin, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/105121
http://hdl.handle.net/10220/20658
http://dx.doi.org/10.1002/anie.201404357
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Institution: Nanyang Technological University
Language: English
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