A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives

A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives

Benzo[b]phosphole derivatives have attracted significant attention for their unique optoelectronic properties with potential for application in materials science. Herein we report a modular approach to a benzo[b]phosphole derivative based on a one-pot sequential coupling of an arylzinc reagent, an a...

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Main Authors: Wu, Bin, Santra, Mithun, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry
Online Access:https://hdl.handle.net/10356/101670
http://hdl.handle.net/10220/19759
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1016702020-03-07T12:34:53Z A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives Wu, Bin Santra, Mithun Yoshikai, Naohiko School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Benzo[b]phosphole derivatives have attracted significant attention for their unique optoelectronic properties with potential for application in materials science. Herein we report a modular approach to a benzo[b]phosphole derivative based on a one-pot sequential coupling of an arylzinc reagent, an alkyne, dichlorophenylphosphine (or phosphorus trichloride and a Grignard reagent), and an oxidant (for example H2O2, S, or Se). The approach allows for the construction of a library of previously inaccessible, structurally diverse benzo[b]phosphole derivatives with unprecedented ease. NRF (Natl Research Foundation, S’pore) 2014-06-13T06:32:44Z 2019-12-06T20:42:34Z 2014-06-13T06:32:44Z 2019-12-06T20:42:34Z 2014 2014 Journal Article Wu, B., Santra, M., & Yoshikai, N. (2014). A Highly Modular One-Pot Multicomponent Approach to Functionalized Benzo[ b ]phosphole Derivatives . Angewandte Chemie International Edition, 53(29), 7543-7546. 1433-7851 https://hdl.handle.net/10356/101670 http://hdl.handle.net/10220/19759 10.1002/anie.201404019 en Angewandte chemie international edition © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Chemistry
spellingShingle DRNTU::Science::Chemistry
Wu, Bin
Santra, Mithun
Yoshikai, Naohiko
A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
description Benzo[b]phosphole derivatives have attracted significant attention for their unique optoelectronic properties with potential for application in materials science. Herein we report a modular approach to a benzo[b]phosphole derivative based on a one-pot sequential coupling of an arylzinc reagent, an alkyne, dichlorophenylphosphine (or phosphorus trichloride and a Grignard reagent), and an oxidant (for example H2O2, S, or Se). The approach allows for the construction of a library of previously inaccessible, structurally diverse benzo[b]phosphole derivatives with unprecedented ease.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wu, Bin
Santra, Mithun
Yoshikai, Naohiko
format Article
author Wu, Bin
Santra, Mithun
Yoshikai, Naohiko
author_sort Wu, Bin
title A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
title_short A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
title_full A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
title_fullStr A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
title_full_unstemmed A highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
title_sort highly modular one-pot multicomponent approach to functionalized benzo[b] phosphole derivatives
publishDate 2014
url https://hdl.handle.net/10356/101670
http://hdl.handle.net/10220/19759
_version_ 1681041650548211712

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