Using monovalent phosphorus compounds to form P-C bonds

Using monovalent phosphorus compounds to form P-C bonds

User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl...

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Bibliographic Details
Main Authors: Ng, Yong Xiang, Mathey, Francois
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Physics
Online Access:https://hdl.handle.net/10356/102735
http://hdl.handle.net/10220/19069
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Institution: Nanyang Technological University
Language: English
Description
Summary:User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P[BOND]H bond that can be used for further transformations.

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