Using monovalent phosphorus compounds to form P-C bonds

Using monovalent phosphorus compounds to form P-C bonds

User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl...

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Main Authors: Ng, Yong Xiang, Mathey, Francois
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Physics
Online Access:https://hdl.handle.net/10356/102735
http://hdl.handle.net/10220/19069
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1027352020-03-07T12:34:54Z Using monovalent phosphorus compounds to form P-C bonds Ng, Yong Xiang Mathey, Francois School of Physical and Mathematical Sciences DRNTU::Science::Physics User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P[BOND]H bond that can be used for further transformations. 2014-04-01T08:18:37Z 2019-12-06T20:59:42Z 2014-04-01T08:18:37Z 2019-12-06T20:59:42Z 2013 2013 Journal Article Ng, Y. X., & Mathey, F. (2013). Using Monovalent Phosphorus Compounds to Form P-C Bonds. Angewandte Chemie International Edition, 52(52), 14140-14142. 1433-7851 https://hdl.handle.net/10356/102735 http://hdl.handle.net/10220/19069 10.1002/anie.201306643 en Angewandte chemie international edition © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Physics
spellingShingle DRNTU::Science::Physics
Ng, Yong Xiang
Mathey, Francois
Using monovalent phosphorus compounds to form P-C bonds
description User friendly P–C: Electrophilic terminal phosphinidene complexes [RP[BOND]W(CO)5] react with Ar[BOND]B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P[BOND]C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P[BOND]H bond that can be used for further transformations.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ng, Yong Xiang
Mathey, Francois
format Article
author Ng, Yong Xiang
Mathey, Francois
author_sort Ng, Yong Xiang
title Using monovalent phosphorus compounds to form P-C bonds
title_short Using monovalent phosphorus compounds to form P-C bonds
title_full Using monovalent phosphorus compounds to form P-C bonds
title_fullStr Using monovalent phosphorus compounds to form P-C bonds
title_full_unstemmed Using monovalent phosphorus compounds to form P-C bonds
title_sort using monovalent phosphorus compounds to form p-c bonds
publishDate 2014
url https://hdl.handle.net/10356/102735
http://hdl.handle.net/10220/19069
_version_ 1681043748670144512

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