One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances

Dual phase titanate/titania nanoparticles undergo phase transformation gradually with the increase of solvothermal synthesis temperature from 100 °C to 200 °C, and eventually are fully transformed into anatase TiO2. The crystal structure change results in the changes of optical absorption, sensitize...

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Main Authors: Cheng, Yu Hua, Gong, Dangguo, Tang, Yuxin, Ho, Jeffery Weng Chye, Tay, Yee Yan, Lau, Wei Siew, Wijaya, Olivia, Lim, Jiexiang, Chen, Zhong
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2014
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Online Access:https://hdl.handle.net/10356/102897
http://hdl.handle.net/10220/24290
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1028972023-07-14T15:50:58Z One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances Cheng, Yu Hua Gong, Dangguo Tang, Yuxin Ho, Jeffery Weng Chye Tay, Yee Yan Lau, Wei Siew Wijaya, Olivia Lim, Jiexiang Chen, Zhong School of Materials Science & Engineering DRNTU::Engineering::Materials Dual phase titanate/titania nanoparticles undergo phase transformation gradually with the increase of solvothermal synthesis temperature from 100 °C to 200 °C, and eventually are fully transformed into anatase TiO2. The crystal structure change results in the changes of optical absorption, sensitizer/dopant formation and surface area of the materials which finally affect the overall dye removal ability. Reactions under dark and light have been conducted to distinguish the contributions of surface adsorption from photocatalytic degradation. The sample synthesized at 160 °C (S160) shows the best performances for both adsorption under dark and photocatalytic degradation of methylene blue (MB) under visible light irradiation. The adsorption mechanism for S160 is determined as monolayer adsorption based on the adsorption isotherm test under dark condition, and an impressive adsorption capacity of 162.19 mg/g is achieved. For the photocatalytic application, this sample at 0.1 g/L loading is also able to degrade 20 ppm MB within 6 hours under the visible light (>420 nm) condition. 2014-12-02T08:40:03Z 2019-12-06T21:01:54Z 2014-12-02T08:40:03Z 2019-12-06T21:01:54Z 2013 2013 Journal Article Cheng, Y. H., Gong, D., Tang, Y., Ho, J. W. C., Tay, Y. Y., Lau, W. S., et al. (2014). One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances. Journal of solid state chemistry, 214, 67-73. 0022-4596 https://hdl.handle.net/10356/102897 http://hdl.handle.net/10220/24290 10.1016/j.jssc.2013.10.036 en Journal of solid state chemistry © 2013 Elsevier Inc. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Solid State Chemistry, Elsevier Inc. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jssc.2013.10.036]. 26 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Engineering::Materials
spellingShingle DRNTU::Engineering::Materials
Cheng, Yu Hua
Gong, Dangguo
Tang, Yuxin
Ho, Jeffery Weng Chye
Tay, Yee Yan
Lau, Wei Siew
Wijaya, Olivia
Lim, Jiexiang
Chen, Zhong
One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances
description Dual phase titanate/titania nanoparticles undergo phase transformation gradually with the increase of solvothermal synthesis temperature from 100 °C to 200 °C, and eventually are fully transformed into anatase TiO2. The crystal structure change results in the changes of optical absorption, sensitizer/dopant formation and surface area of the materials which finally affect the overall dye removal ability. Reactions under dark and light have been conducted to distinguish the contributions of surface adsorption from photocatalytic degradation. The sample synthesized at 160 °C (S160) shows the best performances for both adsorption under dark and photocatalytic degradation of methylene blue (MB) under visible light irradiation. The adsorption mechanism for S160 is determined as monolayer adsorption based on the adsorption isotherm test under dark condition, and an impressive adsorption capacity of 162.19 mg/g is achieved. For the photocatalytic application, this sample at 0.1 g/L loading is also able to degrade 20 ppm MB within 6 hours under the visible light (>420 nm) condition.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Cheng, Yu Hua
Gong, Dangguo
Tang, Yuxin
Ho, Jeffery Weng Chye
Tay, Yee Yan
Lau, Wei Siew
Wijaya, Olivia
Lim, Jiexiang
Chen, Zhong
format Article
author Cheng, Yu Hua
Gong, Dangguo
Tang, Yuxin
Ho, Jeffery Weng Chye
Tay, Yee Yan
Lau, Wei Siew
Wijaya, Olivia
Lim, Jiexiang
Chen, Zhong
author_sort Cheng, Yu Hua
title One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances
title_short One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances
title_full One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances
title_fullStr One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances
title_full_unstemmed One-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances
title_sort one-pot solvothermal synthesis of dual-phase titanate/titania nanoparticles and their adsorption and photocatalytic performances
publishDate 2014
url https://hdl.handle.net/10356/102897
http://hdl.handle.net/10220/24290
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