PhI(OAc)2 mediated radical trifluoromethylation of vinyl azides with Me3SiCF3

• Main Authors: Wang, Yi-Feng, Lonca, Geoffroy Hervé, Chiba, Shunsuke
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2014
• 主題: DRNTU::Science::Mathematics
• 在線閱讀: https://hdl.handle.net/10356/103036; http://hdl.handle.net/10220/19137

The fluorine-containing organic motif is becoming privileged in pharmaceuticals, agrochemicals, and functional materials, owing to its unique properties such as electron-withdrawing character, metabolic stability, and lipophilicity. Described herein is the PhI(OAc)2-mediated radical trifluoromethyla...