Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles

• Main Author: Chiba, Shunsuke
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Carbanions
• Online Access: https://hdl.handle.net/10356/106626; http://hdl.handle.net/10220/25060
• Institution: Nanyang Technological University

Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(iii)-catalyzed...