Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles

Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(iii)-catalyzed...

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Main Author: Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
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Online Access:https://hdl.handle.net/10356/106626
http://hdl.handle.net/10220/25060
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1066262023-02-28T19:37:02Z Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles Chiba, Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Carbanions Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(iii)-catalyzed radical reactions. 2015-02-16T01:18:22Z 2019-12-06T22:15:09Z 2015-02-16T01:18:22Z 2019-12-06T22:15:09Z 2012 2012 Journal Article Chiba, S. (2012). Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles. CHIMIA, 66(6), 377-381. 0009-4293 https://hdl.handle.net/10356/106626 http://hdl.handle.net/10220/25060 10.2533/chimia.2012.377 en CHIMIA © 2012 Swiss Chemical Society. This paper was published in CHIMIA and is made available as an electronic reprint (preprint) with permission of Swiss Chemical Society. The paper can be found at the following official DOI: [http://dx.doi.org/10.2533/chimia.2012.377].  One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry::Carbanions
spellingShingle DRNTU::Science::Chemistry::Organic chemistry::Carbanions
Chiba, Shunsuke
Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
description Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(iii)-catalyzed radical reactions.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Chiba, Shunsuke
format Article
author Chiba, Shunsuke
author_sort Chiba, Shunsuke
title Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
title_short Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
title_full Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
title_fullStr Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
title_full_unstemmed Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
title_sort mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
publishDate 2015
url https://hdl.handle.net/10356/106626
http://hdl.handle.net/10220/25060
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