Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols

Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described.

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Bibliographic Details
Main Authors: Zhang, Feng-Lian, Zhu, Xu, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/98598
http://hdl.handle.net/10220/38585
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Institution: Nanyang Technological University
Language: English