Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols

Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described.

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Bibliographic Details
Main Authors:	Zhang, Feng-Lian, Zhu, Xu, Chiba, Shunsuke
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2015
Subjects:	DRNTU::Science::Chemistry::Organic chemistry
Online Access:	https://hdl.handle.net/10356/98598 http://hdl.handle.net/10220/38585
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Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-98598
record_format	dspace
spelling	sg-ntu-dr.10356-985982023-02-28T19:22:27Z Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described. MOE (Min. of Education, S’pore) Accepted version 2015-09-04T04:15:10Z 2019-12-06T19:57:17Z 2015-09-04T04:15:10Z 2019-12-06T19:57:17Z 2015 2015 Journal Article Zhang, F.-L., Zhu, X., & Chiba, S. (2015). Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols. Organic Letters, 17(12), 3138-3141. 1523-7060 https://hdl.handle.net/10356/98598 http://hdl.handle.net/10220/38585 10.1021/acs.orglett.5b01458 en Organic letters © 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acs.orglett.5b01458]. 4 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
description	Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke
format	Article
author	Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke
author_sort	Zhang, Feng-Lian
title	Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
title_short	Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
title_full	Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
title_fullStr	Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
title_full_unstemmed	Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
title_sort	tf 2 nh-catalyzed amide synthesis from vinyl azides and alcohols
publishDate	2015
url	https://hdl.handle.net/10356/98598 http://hdl.handle.net/10220/38585
_version_	1759857318184353792

Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols

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