Manganese(III)-mediated reactions of vinyl azides and 1,3-dicarbonyl compounds or cyclopropanols : synthesis of azaheterocycles

• المؤلف الرئيسي: Wang, Yifeng
• مؤلفون آخرون: Chiba Shunsuke
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2011
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/42871

In this thesis, the author describes efficient methods to synthesize azaheterocycles by using readily accessible vinyl azides as fundamental substrates. These methods involve iminyl radicals as key intermediates, which are generated by the addition of α- or β-carbonyl radicals to the C═C bond of vin...