Manganese(III)-mediated reactions of vinyl azides and 1,3-dicarbonyl compounds or cyclopropanols : synthesis of azaheterocycles

• Main Author: Wang, Yifeng
• Other Authors: Chiba Shunsuke
• Format: Theses and Dissertations
• Language: English
• Published: 2011
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
• Online Access: https://hdl.handle.net/10356/42871
• Institution: Nanyang Technological University

In this thesis, the author describes efficient methods to synthesize azaheterocycles by using readily accessible vinyl azides as fundamental substrates. These methods involve iminyl radicals as key intermediates, which are generated by the addition of α- or β-carbonyl radicals to the C═C bond of vin...