Mechanism of phosphinidene complex arylation by arylboronic acids
The arylation reaction of terminal phosphinidene complexes [RP-W(CO)5] by arylboronic acids is very sensitive to steric hindrance and the electronic properties of the substituents on the aryl ring. On the basis of DFT calculations and additional experiments, it seems that the mechanism involves firs...
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Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
2014
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/103103 http://hdl.handle.net/10220/24380 |
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Institution: | Nanyang Technological University |
Language: | English |