Mechanism of phosphinidene complex arylation by arylboronic acids

• المؤلفون الرئيسيون: Ng, Yong Xiang, Mathey, Francois
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/103103; http://hdl.handle.net/10220/24380

The arylation reaction of terminal phosphinidene complexes [RP-W(CO)5] by arylboronic acids is very sensitive to steric hindrance and the electronic properties of the substituents on the aryl ring. On the basis of DFT calculations and additional experiments, it seems that the mechanism involves firs...