Mechanism of phosphinidene complex arylation by arylboronic acids

The arylation reaction of terminal phosphinidene complexes [RP-W(CO)5] by arylboronic acids is very sensitive to steric hindrance and the electronic properties of the substituents on the aryl ring. On the basis of DFT calculations and additional experiments, it seems that the mechanism involves firs...

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Main Authors: Ng, Yong Xiang, Mathey, Francois
其他作者: School of Physical and Mathematical Sciences
格式: Article
語言:English
出版: 2014
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在線閱讀:https://hdl.handle.net/10356/103103
http://hdl.handle.net/10220/24380
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