One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation

One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation

A concise and highly efficient strategy for the synthesis of N-glycosyl imidazole analogues is reported. This reaction is based on a palladium catalysed decarboxylative allylation and three steps, namely, carbamation, decarboxylation and allylation are involved. All the substrates can afford the des...

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Main Authors: Xiang, Shaohua, He, Jingxi, Ma, Jimei, Liu, Xue-Wei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Online Access:https://hdl.handle.net/10356/103109
http://hdl.handle.net/10220/24357
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1031092023-02-28T19:23:06Z One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation Xiang, Shaohua He, Jingxi Ma, Jimei Liu, Xue-Wei School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis A concise and highly efficient strategy for the synthesis of N-glycosyl imidazole analogues is reported. This reaction is based on a palladium catalysed decarboxylative allylation and three steps, namely, carbamation, decarboxylation and allylation are involved. All the substrates can afford the desired products with excellent yields and selectivities. NMRC (Natl Medical Research Council, S’pore) MOH (Min. of Health, S’pore) Accepted version 2014-12-09T01:52:44Z 2019-12-06T21:05:47Z 2014-12-09T01:52:44Z 2019-12-06T21:05:47Z 2014 2014 Journal Article Xiang, S., He, J., Ma, J., & Liu, X.-W. (2014). One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation. Chemical communications, 50(32), 4222-4224. https://hdl.handle.net/10356/103109 http://hdl.handle.net/10220/24357 10.1039/c3cc48041k en Chemical communications © 2014 The Authors. This is the author created version of a work that has been peer reviewed and accepted for publication in Chemical Communications, published by Royal Society of Chemistry on behalf of The Authors. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1039/c3cc48041k]. 3 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
spellingShingle DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Xiang, Shaohua
He, Jingxi
Ma, Jimei
Liu, Xue-Wei
One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
description A concise and highly efficient strategy for the synthesis of N-glycosyl imidazole analogues is reported. This reaction is based on a palladium catalysed decarboxylative allylation and three steps, namely, carbamation, decarboxylation and allylation are involved. All the substrates can afford the desired products with excellent yields and selectivities.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Xiang, Shaohua
He, Jingxi
Ma, Jimei
Liu, Xue-Wei
format Article
author Xiang, Shaohua
He, Jingxi
Ma, Jimei
Liu, Xue-Wei
author_sort Xiang, Shaohua
title One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
title_short One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
title_full One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
title_fullStr One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
title_full_unstemmed One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
title_sort one-pot synthesis of β-n-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
publishDate 2014
url https://hdl.handle.net/10356/103109
http://hdl.handle.net/10220/24357
_version_ 1759856857748340736

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