Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential
A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated.
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2014
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sg-ntu-dr.10356-1037942023-02-28T19:37:25Z Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential Gan, Kennard Sadeer, Abdul Xu, Chang Li, Yongxin Pullarkat, Sumod A. School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated. MOE (Min. of Education, S’pore) Accepted version 2014-12-26T08:55:43Z 2019-12-06T21:20:25Z 2014-12-26T08:55:43Z 2019-12-06T21:20:25Z 2014 2014 Journal Article Gan, K., Sadeer, A., Xu, C., Li, Y., & Pullarkat, S. A. (2014). Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential. Organometallics, 33(19), 5074-5076. https://hdl.handle.net/10356/103794 http://hdl.handle.net/10220/24560 10.1021/om5007215 en Organometallics © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om5007215]. 4 p. application/pdf |
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DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
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DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Gan, Kennard Sadeer, Abdul Xu, Chang Li, Yongxin Pullarkat, Sumod A. Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential |
| description |
A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Gan, Kennard Sadeer, Abdul Xu, Chang Li, Yongxin Pullarkat, Sumod A. |
| format |
Article |
| author |
Gan, Kennard Sadeer, Abdul Xu, Chang Li, Yongxin Pullarkat, Sumod A. |
| author_sort |
Gan, Kennard |
| title |
Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential |
| title_short |
Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential |
| title_full |
Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential |
| title_fullStr |
Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential |
| title_full_unstemmed |
Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential |
| title_sort |
asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential |
| publishDate |
2014 |
| url |
https://hdl.handle.net/10356/103794 http://hdl.handle.net/10220/24560 |
| _version_ |
1759858347898568704 |