Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct : a mesoionic germylene equivalent
An autoionization of germanium dichloride/dioxane complex with an imino-N-heterocyclic carbene ligand (L) afforded a novel germyliumylidene ion, [(L)GeCl]+[GeCl3]−, which was fully characterized. Reduction of the germyliumylidene ion with potassium graphite produced a cyclic species [(L)Ge], which c...
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| Main Authors: | , , , |
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| 格式: | Article |
| 語言: | English |
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2015
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| 主題: | |
| 在線閱讀: | https://hdl.handle.net/10356/103941 http://hdl.handle.net/10220/24633 |
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| 機構: | Nanyang Technological University |
| 語言: | English |