Syntheses, crystal structures and properties of series of 4d–4fln(III)–Ag(I) heterometallic coordination polymers

Syntheses, crystal structures and properties of series of 4d–4fln(III)–Ag(I) heterometallic coordination polymers

By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, {[LnIIIAgI(na)(ina)(ox)]·2(H2O)}n [Ln=Sm(1), Eu(2), Gd(3), Tb(4),...

Full description

Saved in:
Bibliographic Details
Main Authors: Ran, Xing-Rui, Wang, Ning, Xie, Wei-Ping, Xiong, Yan-Ju, Cheng, Qian, Long, Yi, Yue, Shan-Tang, Liu, Ying-Liang
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2015
Subjects:
DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry
Online Access:https://hdl.handle.net/10356/105085
http://hdl.handle.net/10220/25869
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
Description
Summary:By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, {[LnIIIAgI(na)(ina)(ox)]·2(H2O)}n [Ln=Sm(1), Eu(2), Gd(3), Tb(4), Dy(5), Ho(6), Y(7), Yb(8)], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail.

Similar Items