Syntheses, crystal structures and properties of series of 4d–4fln(III)–Ag(I) heterometallic coordination polymers

• Main Authors: Ran, Xing-Rui, Wang, Ning, Xie, Wei-Ping, Xiong, Yan-Ju, Cheng, Qian, Long, Yi, Yue, Shan-Tang, Liu, Ying-Liang
• Other Authors: School of Materials Science & Engineering
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Physical chemistry::Solid state chemistry
• Online Access: https://hdl.handle.net/10356/105085; http://hdl.handle.net/10220/25869
• Institution: Nanyang Technological University

By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, {[LnIIIAgI(na)(ina)(ox)]·2(H2O)}n [Ln=Sm(1), Eu(2), Gd(3), Tb(4), Dy(5), Ho(6), Y(7), Yb(8)], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail.