Acyclic amido-containing silanechalcogenones
Reactions of the amidinate-stabilized silicon(II) bis(trimethylsilyl)amide [LSiN(SiMe3)2], {L = PhC(NtBu)2, 1} with a stiochiometric amount of elemental sulfur, selenium and tellurium afforded the first stable silanechalcogenones comprising an acyclic amido substituent [L{N(SiMe3)2}Si=E] {E = S (2),...
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2015
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sg-ntu-dr.10356-1052142019-12-06T21:47:34Z Acyclic amido-containing silanechalcogenones Chan, Yuk-Chi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Inorganic chemistry::Analysis Reactions of the amidinate-stabilized silicon(II) bis(trimethylsilyl)amide [LSiN(SiMe3)2], {L = PhC(NtBu)2, 1} with a stiochiometric amount of elemental sulfur, selenium and tellurium afforded the first stable silanechalcogenones comprising an acyclic amido substituent [L{N(SiMe3)2}Si=E] {E = S (2), Se (3) or Te (4)}. All compounds were characterized by X-ray crystallography and multinuclear NMR spectroscopy. The results illustrate that these compounds possess some silicon–chalcogen double bond character. 2015-06-18T04:43:06Z 2019-12-06T21:47:34Z 2015-06-18T04:43:06Z 2019-12-06T21:47:34Z 2015 2015 Journal Article Chan, Y.-C., Li, Y., Ganguly, R., & So, C.-W. (2015). Acyclic amido-containing silanechalcogenones. European journal of inorganic chemistry, 2015(23), 3821-3824. 1434-1948 https://hdl.handle.net/10356/105214 http://hdl.handle.net/10220/25963 http://dx.doi.org/10.1002/ejic.201500108 en European journal of inorganic chemistry © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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DRNTU::Science::Chemistry::Inorganic chemistry::Analysis Chan, Yuk-Chi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai Acyclic amido-containing silanechalcogenones |
| description |
Reactions of the amidinate-stabilized silicon(II) bis(trimethylsilyl)amide [LSiN(SiMe3)2], {L = PhC(NtBu)2, 1} with a stiochiometric amount of elemental sulfur, selenium and tellurium afforded the first stable silanechalcogenones comprising an acyclic amido substituent [L{N(SiMe3)2}Si=E] {E = S (2), Se (3) or Te (4)}. All compounds were characterized by X-ray crystallography and multinuclear NMR spectroscopy. The results illustrate that these compounds possess some silicon–chalcogen double bond character. |
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School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Chan, Yuk-Chi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai |
| format |
Article |
| author |
Chan, Yuk-Chi Li, Yongxin Ganguly, Rakesh So, Cheuk-Wai |
| author_sort |
Chan, Yuk-Chi |
| title |
Acyclic amido-containing silanechalcogenones |
| title_short |
Acyclic amido-containing silanechalcogenones |
| title_full |
Acyclic amido-containing silanechalcogenones |
| title_fullStr |
Acyclic amido-containing silanechalcogenones |
| title_full_unstemmed |
Acyclic amido-containing silanechalcogenones |
| title_sort |
acyclic amido-containing silanechalcogenones |
| publishDate |
2015 |
| url |
https://hdl.handle.net/10356/105214 http://hdl.handle.net/10220/25963 http://dx.doi.org/10.1002/ejic.201500108 |
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