Acyclic amido-containing silanechalcogenones

• Main Authors: Chan, Yuk-Chi, Li, Yongxin, Ganguly, Rakesh, So, Cheuk-Wai
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Inorganic chemistry::Analysis
• Online Access: https://hdl.handle.net/10356/105214; http://hdl.handle.net/10220/25963; http://dx.doi.org/10.1002/ejic.201500108
• Institution: Nanyang Technological University

Reactions of the amidinate-stabilized silicon(II) bis(trimethylsilyl)amide [LSiN(SiMe3)2], {L = PhC(NtBu)2, 1} with a stiochiometric amount of elemental sulfur, selenium and tellurium afforded the first stable silanechalcogenones comprising an acyclic amido substituent [L{N(SiMe3)2}Si=E] {E = S (2),...