Synthesis of N-heterocyclic carbene stabilized catecholatoborenium cations by ligand substitution

• Main Authors: Do, Dinh Cao Huan, Muthaiah, Senthilkumar, Ganguly, Rakesh, Vidović, Dragoslav
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2014
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• Online Access: https://hdl.handle.net/10356/105349; http://hdl.handle.net/10220/20516

Ligand substitution is not a common procedure for the preparation of different borenium cations. This work demonstrates that the chloride ligands of several NHC-stabilized dichloroborenium cations [NHC·BCl2][X] (NHC = (R′C)2(NR)2C; 1, R = iPr, R′ = H; 2, R = iPr, R′ = Me; 3, R = tBu, R′ = H; X = AlC...