Chiral pyridine-N-heterocyclic carbene based palladacycle for homogeneous catalysis : synthesis, characterization and application.

• 主要作者: Ng, Kim Hong.
• 其他作者: Leung Pak Hing
• 格式: Final Year Project
• 語言: English
• 出版: 2010
• 主題: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• 在線閱讀: http://hdl.handle.net/10356/40821
• 機構: Nanyang Technological University

Optical resolution (using enantiopure amino acids) was used as a mean to resolve a racemic six-membered bidentate pyridine-N-heterocyclic based palladacycle. Two different solvent systems were found to be able to crystallize out one of the diastereomer, (SC,SC)-5 successfully, leaving the mother liq...