Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines

• Main Author: Huang, Yinhua
• Other Authors: Leung Pak Hing
• Format: Theses and Dissertations
• Language: English
• Published: 2012
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• Online Access: https://hdl.handle.net/10356/48148
• Institution: Nanyang Technological University

This thesis, consisting of three chapters, describes the development of asymmetric C-P bond formation (including C*-P, C*-P*, and double C*-P) via hydrophosphination reactions activated by palladacycles. This methodology provides the access to a series of tertiary C-stereogenic monophosphines, C- an...