Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines

Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines

This thesis, consisting of three chapters, describes the development of asymmetric C-P bond formation (including C*-P, C*-P*, and double C*-P) via hydrophosphination reactions activated by palladacycles. This methodology provides the access to a series of tertiary C-stereogenic monophosphines, C- an...

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Bibliographic Details
Main Author: Huang, Yinhua
Other Authors: Leung Pak Hing
Format: Theses and Dissertations
Language:English
Published: 2012
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:https://hdl.handle.net/10356/48148
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Institution: Nanyang Technological University
Language: English
Description
Summary:This thesis, consisting of three chapters, describes the development of asymmetric C-P bond formation (including C*-P, C*-P*, and double C*-P) via hydrophosphination reactions activated by palladacycles. This methodology provides the access to a series of tertiary C-stereogenic monophosphines, C- and P-stereogenic monophosphines, and C-stereogenic PCP diphosphines (chiral PCP pincer ligands) in high yields with excellent stereoselectivities.

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