Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines

Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines

This thesis, consisting of three chapters, describes the development of asymmetric C-P bond formation (including C*-P, C*-P*, and double C*-P) via hydrophosphination reactions activated by palladacycles. This methodology provides the access to a series of tertiary C-stereogenic monophosphines, C- an...

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Main Author: Huang, Yinhua
Other Authors: Leung Pak Hing
Format: Theses and Dissertations
Language:English
Published: 2012
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:https://hdl.handle.net/10356/48148
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-481482023-02-28T23:35:14Z Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines Huang, Yinhua Leung Pak Hing School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds This thesis, consisting of three chapters, describes the development of asymmetric C-P bond formation (including C*-P, C*-P*, and double C*-P) via hydrophosphination reactions activated by palladacycles. This methodology provides the access to a series of tertiary C-stereogenic monophosphines, C- and P-stereogenic monophosphines, and C-stereogenic PCP diphosphines (chiral PCP pincer ligands) in high yields with excellent stereoselectivities. DOCTOR OF PHILOSOPHY (SPMS) 2012-03-19T03:08:51Z 2012-03-19T03:08:51Z 2012 2012 Thesis Huang, Y. H. (2012). Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/48148 10.32657/10356/48148 en 202 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
spellingShingle DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Huang, Yinhua
Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
description This thesis, consisting of three chapters, describes the development of asymmetric C-P bond formation (including C*-P, C*-P*, and double C*-P) via hydrophosphination reactions activated by palladacycles. This methodology provides the access to a series of tertiary C-stereogenic monophosphines, C- and P-stereogenic monophosphines, and C-stereogenic PCP diphosphines (chiral PCP pincer ligands) in high yields with excellent stereoselectivities.
author2 Leung Pak Hing
author_facet Leung Pak Hing
Huang, Yinhua
format Theses and Dissertations
author Huang, Yinhua
author_sort Huang, Yinhua
title Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
title_short Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
title_full Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
title_fullStr Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
title_full_unstemmed Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
title_sort asymmetric c-p bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
publishDate 2012
url https://hdl.handle.net/10356/48148
_version_ 1759853703204962304

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