Chiral pyridine-N-heterocyclic carbene based palladacycle for homogeneous catalysis : synthesis, characterization and application.

• المؤلف الرئيسي: Ng, Kim Hong.
• مؤلفون آخرون: Leung Pak Hing
• التنسيق: Final Year Project
• اللغة: English
• منشور في: 2010
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/40821

Optical resolution (using enantiopure amino acids) was used as a mean to resolve a racemic six-membered bidentate pyridine-N-heterocyclic based palladacycle. Two different solvent systems were found to be able to crystallize out one of the diastereomer, (SC,SC)-5 successfully, leaving the mother liq...