Boron-based stepwise dioxygen activation with 1,4,2,5-diazadiborinine
Activation of dioxygen (O2) by 1,4,2,5-diazadiborinine 1 is reported. Two boron centers in 1 undergo a formal [4 + 2] cycloaddition with O2 at room temperature affording a bicyclo[2.2.2] molecule 2 featuring a B–O–O–B unit. Treatment of 2 with an additional equivalent of 1 leads to the cleavage of t...
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| Main Authors: | , |
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| 格式: | Article |
| 語言: | English |
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2019
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| 主題: | |
| 在線閱讀: | https://hdl.handle.net/10356/105504 http://hdl.handle.net/10220/47811 |
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| 機構: | Nanyang Technological University |
| 語言: | English |