Engineering the frontier orbitals of a diazadiborinine for facile activation of H2, NH3, and an isonitrile

Engineering the frontier orbitals of a diazadiborinine for facile activation of H2, NH3, and an isonitrile

An annulated 1,3,2,5‐diazadiborinine with 14 π electrons has been synthesized and fully characterized. Experimental and computational studies revealed that this compound features a rather small HOMO–LUMO gap, which leads to enhanced reactivity towards small molecules. Thus, the 1,3,2,5‐diazadiborini...

Full description

Saved in:
Bibliographic Details
Main Authors: Su, Yuanting, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Boron
Electronic Structure
Online Access:https://hdl.handle.net/10356/137706
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/137706

Similar Items