Engineering the frontier orbitals of a diazadiborinine for facile activation of H2, NH3, and an isonitrile
An annulated 1,3,2,5‐diazadiborinine with 14 π electrons has been synthesized and fully characterized. Experimental and computational studies revealed that this compound features a rather small HOMO–LUMO gap, which leads to enhanced reactivity towards small molecules. Thus, the 1,3,2,5‐diazadiborini...
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Main Authors: | Su, Yuanting, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2020
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/137706 |
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Institution: | Nanyang Technological University |
Language: | English |
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