Enhancement in the performance of ultrathin hematite photoanode for water splitting by an oxide underlayer

A 2-nm thick Nb2O5 underlayer deposited by atomic layer deposition increases the charge separation efficiency and the photovoltage of ultrathin hematite films by suppressing electron back injection. Absorbed photon-to-current efficiencies (APCE) as high as 40%, which are one of the highest ever repo...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Grätzel, Michael, Hisatomi, Takashi, Dotan, Hen, Stefik, Morgan, Sivula, Kevin, Rothschild, Avner, Mathews, Nripan
مؤلفون آخرون: School of Materials Science & Engineering
التنسيق: مقال
اللغة:English
منشور في: 2013
الوصول للمادة أونلاين:https://hdl.handle.net/10356/106608
http://hdl.handle.net/10220/10667
الوسوم: إضافة وسم
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المؤسسة: Nanyang Technological University
اللغة: English
الوصف
الملخص:A 2-nm thick Nb2O5 underlayer deposited by atomic layer deposition increases the charge separation efficiency and the photovoltage of ultrathin hematite films by suppressing electron back injection. Absorbed photon-to-current efficiencies (APCE) as high as 40%, which are one of the highest ever reported with hematite photoanodes, are obtained at 400 nm at +1.43 V vs. RHE.