Palladium-catalyzed stereoselective C-glycosylation of glycals with sodium arylsulfinates

• المؤلفون الرئيسيون: Ma, Jimei, Xiang, Shaohua, Jiang, Hong, Liu, Xue-Wei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2015
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/106693; http://hdl.handle.net/10220/25083; http://dx.doi.org/10.1002/ejoc.201403550
• المؤسسة: Nanyang Technological University

An efficient glycosylation method to synthesize 2-deoxy-C-aryl glycosides was developed. This C-glycosylation strategy is based on a palladium-catalyzed desulfitative Ferrier-type coupling reaction of glycals and sodium arylsulfinates. A series of C-aryl glycosides were obtained in moderate to good...