Reversing the stereoselectivity of a palladium-catalyzed O-glycosylation through an inner-sphere or outer-sphere pathway

An efficient and concise method for the construction of various O-glycosidic bonds by a palladium-catalyzed reaction with a 3-O-picoloyl glucal has been developed. The stereochemistry of the anomeric center derives from either an inner-sphere or outer-sphere pathway. Harder nucleophiles, such as ali...

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Bibliographic Details
Main Authors: Xiang, Shaohua, Hoang, Kim Le Mai, He, Jingxi, Tan, Yu Jia, Liu, Xue-Wei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/106703
http://hdl.handle.net/10220/25100
http://dx.doi.org/10.1002/anie.201408739
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Institution: Nanyang Technological University
Language: English
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