Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents

Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents

Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)2 and PhI(NMs2)2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.

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Bibliographic Details
Main Authors: Chen, Hui, Kaga, Atsushi, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
DRNTU::Science::Chemistry::Organic chemistry
Online Access:https://hdl.handle.net/10356/106743
http://hdl.handle.net/10220/25070
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/106743
http://hdl.handle.net/10220/25070

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