Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)2 and PhI(NMs2)2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.
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| Main Authors: | , , |
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| 格式: | Article |
| 語言: | English |
| 出版: |
2015
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| 主題: | |
| 在線閱讀: | https://hdl.handle.net/10356/106743 http://hdl.handle.net/10220/25070 |
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| 機構: | Nanyang Technological University |
| 語言: | English |