Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents

Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents

Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)2 and PhI(NMs2)2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.

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Main Authors: Chen, Hui, Kaga, Atsushi, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
DRNTU::Science::Chemistry::Organic chemistry
Online Access:https://hdl.handle.net/10356/106743
http://hdl.handle.net/10220/25070
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1067432023-02-28T19:44:56Z Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents Chen, Hui Kaga, Atsushi Chiba, Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)2 and PhI(NMs2)2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes. Accepted version 2015-02-16T09:22:52Z 2019-12-06T22:17:27Z 2015-02-16T09:22:52Z 2019-12-06T22:17:27Z 2014 2014 Journal Article Chen, H., Kaga, A., & Chiba, S. (2014). Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents. Organic letters, 16(23), 6136-6139. https://hdl.handle.net/10356/106743 http://hdl.handle.net/10220/25070 10.1021/ol503000c en Organic letters © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/ol503000c]. 8 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry
spellingShingle DRNTU::Science::Chemistry::Organic chemistry
Chen, Hui
Kaga, Atsushi
Chiba, Shunsuke
Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
description Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)2 and PhI(NMs2)2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Chen, Hui
Kaga, Atsushi
Chiba, Shunsuke
format Article
author Chen, Hui
Kaga, Atsushi
Chiba, Shunsuke
author_sort Chen, Hui
title Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
title_short Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
title_full Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
title_fullStr Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
title_full_unstemmed Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
title_sort diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(iii) reagents
publishDate 2015
url https://hdl.handle.net/10356/106743
http://hdl.handle.net/10220/25070
_version_ 1759853949194600448

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