Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations

• 主要作者: Yoshikai, Naohiko
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2015
• 主題: DRNTU::Science::Chemistry::Physical chemistry::Catalysis
• 在線閱讀: https://hdl.handle.net/10356/106968; http://hdl.handle.net/10220/25272; http://dx.doi.org/10.1002/cctc.201403017
• 機構: Nanyang Technological University

Directed activation: Cationic Cp*CoIII (Cp*=1,2,3,4,5-pentamethylcyclopentadienyl) complexes, either well-defined or in situ-generated, promote catalytic functionalization of arene C[BOND]H bonds with a variety of electrophilic reaction partners by directed C[BOND]H activation. These complexes not o...