Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations
Directed activation: Cationic Cp*CoIII (Cp*=1,2,3,4,5-pentamethylcyclopentadienyl) complexes, either well-defined or in situ-generated, promote catalytic functionalization of arene C[BOND]H bonds with a variety of electrophilic reaction partners by directed C[BOND]H activation. These complexes not o...
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sg-ntu-dr.10356-1069682019-12-06T22:22:04Z Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations Yoshikai, Naohiko School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Physical chemistry::Catalysis Directed activation: Cationic Cp*CoIII (Cp*=1,2,3,4,5-pentamethylcyclopentadienyl) complexes, either well-defined or in situ-generated, promote catalytic functionalization of arene C[BOND]H bonds with a variety of electrophilic reaction partners by directed C[BOND]H activation. These complexes not only emulate known reaction patterns of Cp*RhIII analogues, but also exhibit remarkable catalytic activity or unique reactivity. DG=Directing group. 2015-03-24T08:37:33Z 2019-12-06T22:22:04Z 2015-03-24T08:37:33Z 2019-12-06T22:22:04Z 2015 2015 Journal Article Yoshikai, N. (2015). Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations. ChemCatChem, 7(5), 732-734. 1867-3880 https://hdl.handle.net/10356/106968 http://hdl.handle.net/10220/25272 http://dx.doi.org/10.1002/cctc.201403017 en ChemCatChem © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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DRNTU::Science::Chemistry::Physical chemistry::Catalysis Yoshikai, Naohiko Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations |
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Directed activation: Cationic Cp*CoIII (Cp*=1,2,3,4,5-pentamethylcyclopentadienyl) complexes, either well-defined or in situ-generated, promote catalytic functionalization of arene C[BOND]H bonds with a variety of electrophilic reaction partners by directed C[BOND]H activation. These complexes not only emulate known reaction patterns of Cp*RhIII analogues, but also exhibit remarkable catalytic activity or unique reactivity. DG=Directing group. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Yoshikai, Naohiko |
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Yoshikai, Naohiko |
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Yoshikai, Naohiko |
title |
Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations |
title_short |
Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations |
title_full |
Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations |
title_fullStr |
Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations |
title_full_unstemmed |
Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations |
title_sort |
cp*co iii -catalyzed c-h activation of (hetero)arenes : expanding the scope of base-metal-catalyzed c-h functionalizations |
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2015 |
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https://hdl.handle.net/10356/106968 http://hdl.handle.net/10220/25272 http://dx.doi.org/10.1002/cctc.201403017 |
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