Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations

Directed activation: Cationic Cp*CoIII (Cp*=1,2,3,4,5-pentamethylcyclopentadienyl) complexes, either well-defined or in situ-generated, promote catalytic functionalization of arene C[BOND]H bonds with a variety of electrophilic reaction partners by directed C[BOND]H activation. These complexes not o...

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Main Author: Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
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Online Access:https://hdl.handle.net/10356/106968
http://hdl.handle.net/10220/25272
http://dx.doi.org/10.1002/cctc.201403017
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1069682019-12-06T22:22:04Z Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations Yoshikai, Naohiko School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Physical chemistry::Catalysis Directed activation: Cationic Cp*CoIII (Cp*=1,2,3,4,5-pentamethylcyclopentadienyl) complexes, either well-defined or in situ-generated, promote catalytic functionalization of arene C[BOND]H bonds with a variety of electrophilic reaction partners by directed C[BOND]H activation. These complexes not only emulate known reaction patterns of Cp*RhIII analogues, but also exhibit remarkable catalytic activity or unique reactivity. DG=Directing group. 2015-03-24T08:37:33Z 2019-12-06T22:22:04Z 2015-03-24T08:37:33Z 2019-12-06T22:22:04Z 2015 2015 Journal Article Yoshikai, N. (2015). Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations. ChemCatChem, 7(5), 732-734. 1867-3880 https://hdl.handle.net/10356/106968 http://hdl.handle.net/10220/25272 http://dx.doi.org/10.1002/cctc.201403017 en ChemCatChem © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Physical chemistry::Catalysis
spellingShingle DRNTU::Science::Chemistry::Physical chemistry::Catalysis
Yoshikai, Naohiko
Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations
description Directed activation: Cationic Cp*CoIII (Cp*=1,2,3,4,5-pentamethylcyclopentadienyl) complexes, either well-defined or in situ-generated, promote catalytic functionalization of arene C[BOND]H bonds with a variety of electrophilic reaction partners by directed C[BOND]H activation. These complexes not only emulate known reaction patterns of Cp*RhIII analogues, but also exhibit remarkable catalytic activity or unique reactivity. DG=Directing group.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Yoshikai, Naohiko
format Article
author Yoshikai, Naohiko
author_sort Yoshikai, Naohiko
title Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations
title_short Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations
title_full Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations
title_fullStr Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations
title_full_unstemmed Cp*Co III -catalyzed C-H activation of (Hetero)arenes : expanding the scope of base-metal-catalyzed C-H functionalizations
title_sort cp*co iii -catalyzed c-h activation of (hetero)arenes : expanding the scope of base-metal-catalyzed c-h functionalizations
publishDate 2015
url https://hdl.handle.net/10356/106968
http://hdl.handle.net/10220/25272
http://dx.doi.org/10.1002/cctc.201403017
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