Os3(CO)11(BiPh3) : the missing link in osmium-bismuth cluster chemistry

• Main Authors: Oh, Suat Ping, Li, Ying-Zhou, Leong, Weng Kee
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• Online Access: https://hdl.handle.net/10356/107295; http://hdl.handle.net/10220/25442
• Institution: Nanyang Technological University

The room temperature reaction of Os3(CO)11(NCCH3) with BiPh3 afforded the substituted derivative Os3(CO)11(BiPh3) which decomposed rapidly. The X-ray crystallographic study is reported, together with that of the stibine and arsine analogues.