Theory of femtosecond coherent double-pump single-molecule spectroscopy : application to light harvesting complexes

• Main Authors: Chen, Lipeng, Gelin, Maxim F., Domcke, Wolfgang, Zhao, Yang
• Other Authors: School of Materials Science & Engineering
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Physical chemistry
• Online Access: https://hdl.handle.net/10356/107369; http://hdl.handle.net/10220/25478
• Institution: Nanyang Technological University

We develop a first principles theoretical description of femtosecond double-pump single-molecule signals of molecular aggregates. We incorporate all singly-excited electronic states and vibrational modes with significant electron-vibrational coupling into a system Hamiltonian and treat the ensuing s...